| Saturday, 28 August 2010 |
| HOME TEAM | | TIME | | AWAY TEAM |
| Hércules | | 23:00 | | Athletic Bilbao |
| Sunday, 29 August 2010 |
| HOME TEAM | | TIME | | AWAY TEAM |
| Málaga | | 01:00 | | Valencia |
| Levante | | 03:00 | | Sevilla |
| Deportivo La Coruña | | 22:00 | | Real Zaragoza |
| Espanyol | | 22:00 | | Getafe |
| Real Sociedad | | 22:00 | | Villarreal |
| Osasuna | | 22:00 | | Almería |
| Monday, 30 August 2010 |
| HOME TEAM | | TIME | | AWAY TEAM |
| Racing Santander | | 00:00 | | Barcelona |
| Mallorca | | 02:00 | | Real Madrid |
| Tuesday, 31 August 2010 |
| HOME TEAM | | TIME | | AWAY TEAM |
| Atlético Madrid | | 03:00 | | Sporting Gijón |
*(GMT+07:00) Bangkok, Hanoi, Jakarta
